Composition & Photodissociative Flux Measurement


Principle Investigator: C.T. McElroy, Environment Canada
Co-investigators: C. Midwinter, Environment Canada; J.C. McConnell, York University

CPFM articles: Profiles and York University Gazette

Instrument TypeUV-visible spectroradiometer
Dimensions 10 cm x 15 cm x 25 cm
Weight xx
Material xx
Dispersive ElementConcave holographic grating
DetectorReticon EG&G 1024-element photodiode array
Fields MeasuredDownwelling Irradiance
Limb Radiance (Horizontal Component)
Limb Radiance (Vertical Component)
Nadir Radiance (Along-track Component)
Nadir Radiance (Cross-track Component)
Field of View
(nadir and limb)
0.1o x 10o
(nadir footprint is 0.035 km x 3.5 km for ER-2 at 20 km)
Spectral Windows375-775 nm - First Order
188-388 nm - Second Order
Effective Spectral Range300-770 nm
Spectral Resolutionabout 1 nm
Wavelength Assignmentsaccurate to 0.05 nm
UncertainitiesAbsolute - about 10%
Relative - about 3%

Historical Perspective
The CPFM was included as part of the large instrumentation suite on the ER-2 in 1992 for the Stratospheric Photochemistry, Aerosols and Dynamics Expedition (SPADE). Its original purpose was to make measurments of the radiation field so that photolysis rates could be calculated directly, as opposed to replying upon numerical radiative transfer models. Other useful early applications of CPFM measurements were measuring the column ozone above the ER-2 and the wavelength-dependent apparent surface reflectivity (albedo). Each of these are relatively straightforward applications of the CPFM data.
The spectral resolution of the CPFM was high enough that the absorption features of ozone, NO2, and BrO could be clearly identified.
Since its inclusion in the SPADE campaign (1992-1993), the CPFM has flown on the ER-2 for ASHOE/MAESA (Antarctic Southern Hemisphere Ozone Experiment/Measurements for Assessing the Effects of Stratospheric Aircraft) in 1994, STRAT (Stratospheric Tracers of Atmospheric Transport) in 1995-96, and POLARIS (Photochemistry of Ozone Loss in the Arctic Region In Summer) in 1997. Furure campaings in which the CPFM will participate include SOLVE (SAGE III Ozone Loss and Validation Experiment) in 1999-2000.

Installation of CPFM on right wing ER-2.

CPFM optical layout.

Mean Radiance (a.k.a. Actinic Flux)
Limb and Nadir Linear Polarization
Apparent Surface Reflectivity

References:
1. McElroy, C.T., C. Midwinter, D.V. Barton, and R.B. Hall, A comparison of J-values estimated by the Composition and Photodissociative Flux Measurement with model calculations, Geophys. Res. Lett., 22 , 1361-1364, 1995.
2. McElroy, C.T., A spectroradiometer for the measurement of direct and scattered solar irradiance on-board the NASA ER-2 high altitude research aircraft, Geophys. Res. Lett., 22 , 1365-1368, 1995.
3. McElroy, C.T., C. Midwinter, D.V. Barton, and R. Hall, Measurement of the column ozone above the NASA ER-2 stratospheric research aircraft, in Atmospheric Ozone , edited by R.D. Bojkov and G. Visconti, Proceedings of the Quadrennial Ozone Symposium, L'Aquila, Italy, September 1996, 943-946, 1998.
4. McLinden, C.A., J.C. McConnell, C.T. McElroy and E. Griffioen, Sensitivity of polarized limb radiances to stratospheric aerosols with application to NASA ER-2 spectroradiometer measurements, in Atmospheric Ozone , edited by R.D. Bojkov and G. Visconti, Proceedings of the Quadrennial Ozone Symposium, L'Aquila, Italy, September 1996, 947-950, 1998.
5. McElroy, C.T., C.A. McLinden, and J.C. McConnell, Evidence of bromine monoxide in the free troposphere during the Arctic polar sunrise, Nature , 397 , 338-341, 1999.
6. McLinden, C.A., J.C. McConnell, C.T. McElroy, and E. Griffioen, Observations of stratospheric aerosol using CPFM polarized limb radiances, J. Atmos. Sci., 56 , 233-240, 1999.
7. McLinden, C.A., J.C. McConnell, E. Griffioen, C.T. McElroy, and L. Pfister, Estimating the wavelength-dependent ocean albedo under clear sky conditions using NASA ER-2 spectroradiometer measurements, J. Geophys. Res., 102, 18801-18811, 1997.
8. McLinden, C.A., Observations of Atmospheric Composition From NASA ER-2 Spectroradiometer Measurements , Ph.D. thesis, York University, Toronto, pp. 298, 1998.


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