Lifetimes and time scales in atmospheric chemistry

TitleLifetimes and time scales in atmospheric chemistry
Publication TypeJournal Article
Year of Publication2007
AuthorsPrather, M. J.
JournalPhilosophical Transactions of the Royal Society a-Mathematical Physical and Engineering Sciences
Volume365
Pagination1705-1726
Date Published07/2007
Type of ArticleProceedings Paper
ISBN Number1364-503X
Accession Numberhttp://apps.isiknowledge.com/InboundService.do?Func=Frame&product=WOS&action=retrieve&SrcApp=EndNote&Init=Yes&SrcAuth=ResearchSoft&mode=FullRecord&UT=000247780800006
Keywords3-dimensional model; age; atmospheric chemistry; ch3br; chemical modes; eigenvalues; gases; lifetimes; ocean; ozone depletion potentials; Prather Modeling Lab; time scales; timescales
Abstract

Atmospheric composition is controlled by the emission, photochemistry and transport of many trace gases. Understanding the time scale as well as the chemical and spatial patterns of perturbations to trace gases is needed to evaluate possible environmental damage (e.g. stratospheric ozone depletion or climate change) caused by anthropogenic emissions. This paper reviews lessons learned from treating global atmospheric chemistry as a linearized system and analysing it in terms of eigenvalues. The results give insight into ow emissions of one trace species cause perturbations to another and how transport and chemistry can alter the time scale of the overall perturbation. Further, the eigenvectors describe the fundamental chemical modes, or patterns, of the atmosphere's chemical response to perturbations.

URLpub/692
Alternate JournalPhilos. Trans. R. Soc. A-Math. Phys. Eng. Sci.
ESS Associations
Research Area: 
Atmospheric Chemistry
Research Lab: 
Prather Research Group